3rd October, 2012
Group A:
At Kiev
Dynamo Kiev (UKR) 2 (Gusev 3, Pivaric 33-og) Dinamo Zagreb (CRO) 0
At Oporto, Portugal
FC Porto (POR) 1 (Rodriguez 83) Paris Saint Germain (FRA) 0
Group B:
At Gelsenkirchen, Germany
Schalke 04 (GER) 2 (Draxler 26, Huntelaar 53-pen) Montpellier (FRA) 2 (Ait Fana 13, S. Camara 90)
At London
Arsenal (ENG) 3 (Gervinho 42, Podolski 56, Ramsey 90+4) Olympiakos (GRE) 1 (Mitroglou 45)
Group C:
At Brussels
Anderlecht (BEL) 0 Malaga (ESP) 3 (Eliseu 45+1, 64, Joaquin 57-pen)
At St Petersburg, Russia
Zenit St-Petersburg (RUS) 2 (Hulk 45+1, Shirokov 49) AC Milan (ITA) 3 (Emanuelson 13, El Shaarawy 16, Hubocan 75-og)
Group D:
At Amsterdam
Ajax (NED) 1 (Moisander 56) Real Madrid (ESP) 4 (Cristiano Ronaldo 42, 79, 81, Benzema 48)
At Manchester, England
Manchester City (ENG) 1 (Balotelli 90-pen) Borussia Dortmund (GER) 1 (Reuss 61)